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RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Membranes Based on PVdF–HFP and Alkylammonium Protic Ionic Liquids: Thermal and Transport Properties

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PII
10.31857/S0044453723010284-1
DOI
10.31857/S0044453723010284
Publication type
Status
Published
Authors
L. E. Shmukler
  • Affiliation: Krestov Institute of Chemistry of Solutions, Russian Academy of Sciences
Volume/ Edition
Volume 97 / Issue number 1
Pages
166-174
Abstract
Casting from a solution is used to obtain proton-conducting membranes based on a poly(vinylidenefluoride-co-hexafluoropropylene) copolymer doped with diethylammonium hydrogen sulfate and diethylammonium mesylate with different levels of doping. An IR spectroscopic study is performed, and the phase behavior of the obtained membranes, their thermal and electrochemical stability, and specific electrical conductivity are investigated. It is established that doping protic ionic liquids into PVdF-HFP copolymer reduces the degree of its crystallinity. It has been shown that all membranes are thermally stable up to 290–300°C, and their conductivity at 145°C varies from 1.6 to 10.4 mS cm–1, depending on the level of doping.
Keywords
протонпроводящие мембраны термические характеристики электропроводность ИК-спектроскопия
Date of publication
12.09.2025
Year of publication
2025
Number of purchasers
0
Views
7

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