RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Destruction of Octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine Under the Influence of Nitrogen-Containing Organic Bases in Dimethylsulfoxide

PII
10.31857/S004445372307021X-1
DOI
10.31857/S004445372307021X
Publication type
Status
Published
Authors
Volume/ Edition
Volume 97 / Issue number 7
Pages
938-943
Abstract
A study is performed of the state of octa(4-tert-butylphenyl)tetrapyrazinoporphyrazine in dimethyl sulfoxide. It is found that the acid–base interaction of partner molecules creates a time-stable complex with proton transfer. It is shown that adding morpholine, piperidine, n-butylamine, and diethylamine to dimethyl sulfoxide results in destruction of this complex, in contrast to adding pyridine, 2-methylpyridine, tert-butylamine, or tri-n-butylamine. The effect the proton-acceptor ability and the spatial structure of the base have on the decomposition of the tetrapyrazinoporphyrazine macrocycle is considered.
Keywords
окта(4-<i>трет</i>-бутилфенил)тетрапиразинопорфиразин диметилсульфоксид циклическое и ациклическое азотсодержащее основание комплекс с переносом протонов кинетика деструкция
Date of publication
13.09.2025
Year of publication
2025
Number of purchasers
0
Views
11

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