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RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Finsler–Lagrange Kinetic Model of the Structurization of a Langmuir Monolayer

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PII
10.31857/S0044453723110183-1
DOI
10.31857/S0044453723110183
Publication type
Status
Published
Authors
N. G. Krylova
  • Affiliation: Belarusian State Agrarian Technical University
G. V. Grushevskaya
  • Affiliation: Belarusian State University
Volume/ Edition
Volume 97 / Issue number 11
Pages
1627-1637
Abstract
A model is proposed for the synthesis of nanocyclic iron coordination complexes on the surface of an aqueous solution of ferric iron salts during a two-dimensional solid (S)–liquid expanded (L') phase transition of first order. Electrocapillary effects in the nucleation kinetics for such Langmuir monolayers are studied in the context of the Finsler–Lagrangian formalism. It is shown that under conditions of rapid compression, an additional local minimum appears in the surface tension potential of the monolayer. This minimum causes supersaturation of the phase and the formation of nuclei (domains) of the crystalline phase with sizes considerably exceeding the critical one, resulting in a plateau on the compression isotherm and the formation of a multidomain monolayer structure. It is established that since the effective charge of hydrated ferrous iron complexes is greater than that of ferric iron complexes, electrocapillary phenomena at the phase boundary lead to the formation of domains of high-spin octahedral ferrous iron complexes with dithionylpyrrole oligomers.
Keywords
ленгмюровский монослой фазовый переход 1-го рода финслер-лагранжева геометрическая модель высокоспиновый октаэдрический координационный комплекс железа
Date of publication
12.09.2025
Year of publication
2025
Number of purchasers
0
Views
10

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