RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Effect of Additions of Mixtures of Sodium Sulfite and Formic and Acetic Acid on the Photocatalytic Reduction of Water with Cadmium Sulfide Suspensions

PII
10.31857/S0044453723120087-1
DOI
10.31857/S0044453723120087
Publication type
Status
Published
Authors
Volume/ Edition
Volume 97 / Issue number 12
Pages
1806-1811
Abstract
The photochemical reduction of water with cadmium sulfide suspensions containing mixtures of sodium sulfite and formic and acetic acid solutions has been studied by electromotive force measurements and gasometry. The sulfite ions are oxidized on the anode in the sulfite–acetate suspensions; the sulfite ions and formic acid, in the sulfite–formate solutions. Hydrogen peroxide was found among the products of the photochemical reaction; it is involved in the oxidation of the radicals of sulfite ions and molecular sulfur of CdS particles and prevents the reduction of water.
Keywords
сульфид кадмия фотокатализатор электродвижущие силы водород пероксид водорода жертвенные реагенты
Date of publication
13.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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