RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Saturated vapor pressures and enthalpies of vaporization of malic acid esters

PII
S0044453725010026-1
DOI
10.31857/S0044453725010026
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 99 / Issue number 1
Pages
23-31
Abstract
The saturated vapor pressures of malic acid diesters and linear С15 alcohols are determined using the transpiration method in the temperature range of 303–369 K. The enthalpies of vaporization of esters at 298.2 K are determined on the basis of the obtained data. Correlations of the enthalpies of vaporization from Kovats indices and number of carbon atoms are obtained. The contributions of the hydroxyl group and intermolecular hydrogen bonds to are estimated. The author’s QSPR method for calculating the values of the enthalpies of vaporization of esters of hydroxy acids is modified.
Keywords
сложные эфиры яблочной кислоты давления насыщенных паров энтальпия испарения QSPR-метод
Date of publication
12.09.2025
Year of publication
2025
Number of purchasers
0
Views
17

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