- PII
- S0044453725030069-1
- DOI
- 10.31857/S0044453725030069
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 99 / Issue number 3
- Pages
- 420-427
- Abstract
- The influence of additives of some organic substances on the crystallization onset temperatures of kerosene fractions (KF) obtained from crude oil (straight-run or SRKF) and in the process of catalytic cracking of heavy oil residues (HKF) is studied by the method of thermodynamic modeling. Normal paraffins CnH2n+2 (n = 9, 11, 16) are used as additives to the KFs, and m-ethylbutylbenzene is used as an aromatic hydrocarbon. It is shown that using the UNIFAC and UNIQUAC models, one can reproduce the experimental data presented in publications and indicating that the addition of normal paraffins to HKF noticeably increases the freezing point when n is 11 and greater. For SRKF, a similar increase occurs starting from n = 16. According to the calculation results, the addition of m-ethylbutylbenzene practically does not affect the crystallization onset temperature.
- Keywords
- температура замерзания авиационный керосин парафины м-этилбутилбензол термодинамическое моделирование UNIFAC UNIQUAC
- Date of publication
- 12.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 9
References
- 1. Kittel H., Straka P., Šimaček P., Kadleček D. // Petroleum Science and Technology. 2022. v. 41 (5). P. 507. DOI: 10.1080/10916466.2022.2061000
- 2. Zabarnick S., Widmor N. // Energy & Fuels. 2001. V. 15. P. 1447. DOI 10.1021/ef010074b
- 3. Coutinho J.A.P., Andersen S.I., Stenby E.H. // Fluid Ph. Eq. 1995. v. 103 p. 23. DOI 10.1016/0378-3812(94)02600-6
- 4. Coutinho J.A.P. // Ind. Eng. Chem. Res. 1998. v. 37. p. 4870. DOI 10.1021/ie980340h
- 5. Coutinho J.A.P., Dauphin C., Daridon J.L. // Fuel. 2000. v. 79. p. 607. DOI 10.1016/S0016-2361(99)00188-X
- 6. Coutinho J.A.P. // Energy & Fuels. 2000. v. 14. p. 625. DOI 10.1021/ef990203c
- 7. Улитько А.В., Волгин С.Н., Ощенко А.П., Соловьев А.В. // Тр. 25 Гос. НИИ МО РФ. 2022. Вып. 60. Т. 75–80 / Под ред. В.А. Маркина. 512 c.
- 8. Weidlicht U., Gmehling J. // Ind. Eng. Chem. Res. 1987. v. 26. p. 1372. DOI 10.1021/ie00067a018
- 9. Gmehling J., Li J., Schiller M. // Ind. Eng. Chem. Res. 1993. v. 32. p. 178. DOI 10.1021/ie00013a024
- 10. G’mehling J., Lohmann J., Jakob A., et al. // Ind. Eng. Chem. Res. 1998. v. 37. p. 4876. DOI 10.1021/ie980347z
- 11. Morgan D.L., Kobayashi R. // Fluid Ph. Eq. 1994. v. 94. p. 51. DOI 10.1016/0378-3812(94)87051-9
- 12. Болотник Т.А. Новые подходы к определению ракетных керосинов в объектах окружающей среды и растениях методом газовой хромато-масс-спектрометрии. Дис. … к. х. н., МГУ им. М.В. Ломоносова, Химический ф-т, М., 2017. 160 с.
