RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

ENTALPIES OF CRYSTALLOHYDRATES OF Mn(CHSO)·2HO, Co(CHSO)·4HO AND Ni(CHSO)·4HO

PII
S3034553725090011-1
DOI
10.7868/S3034553725090011
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 99 / Issue number 9
Pages
1287-1292
Abstract
Crystal hydrates of Mn(CHSO)·2HO, Co(CHSO)·4HO and Ni(CHSO)·4HO were synthesized and identified by X-ray phase analysis, inductively coupled plasma atomic emission spectroscopy and thermogravimetry. The enthalpies of dissolution in water at 298.15 K were determined by dissolution calorimetry and the standard enthalpies of formation of crystalline hydrates of manganese, cobalt and nickel methanesulfonates were calculated. The enthalpic contribution of the methanesulfonate ion to the enthalpy of crystalline methanesulfonate formation in an additive scheme was estimated from the data obtained.
Keywords
энтальпия растворения стандартная энтальпия образования кристаллогидрат метансульфонаты переходных элементов
Date of publication
13.03.2026
Year of publication
2026
Number of purchasers
0
Views
33

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