RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

CHEMICAL EQUILIBRIA IN THE HETEROGENEOUS REGION OF THE ACETIC ACID - -BUTYL ALCOHOL - -BUTYL ACETATE - WATER SYSTEM AT 298.15 K AND ATMOSPHERIC PRESSURE

PII
S3034553725100055-1
DOI
10.7868/S3034553725100055
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 99 / Issue number 10
Pages
1488-1496
Abstract
This work is devoted to studying the compositions of coexisting phases in chemical equilibrium at 298.15 K and atmospheric pressure. The system under investigation is acetic acid - -butyl alcohol - -butyl acetate - water. The esterification/hydrolysis reaction was carried out in the presence of a catalyst (hydrochloric acid). All results are presented in the corresponding concentration spaces. For better visualization, the compositions of chemically equilibrated phases are shown in the square of concentration α-variables. A comparative analysis of the obtained results is provided. Correlation of the experimental data using the NRTL model demonstrated satisfactory agreement between the calculated and experimental compositions.
Keywords
химическое равновесие фазовое равновесие жидкость-жидкость н-бутиловый спирт н-бутилацетат NRTL
Date of publication
10.04.2025
Year of publication
2025
Number of purchasers
0
Views
38

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