- PII
- 10.31857/S0044453723020127-1
- DOI
- 10.31857/S0044453723020127
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 97 / Issue number 2
- Pages
- 223-226
- Abstract
- A study is performed of the catalytic properties of bimetallic nanoparticles based on palladium and a base metal (silver or copper) supported on alumina modified with chitosan in the selective hydrogenation of pyridine and derivatives of it with the formation of piperidine and derivatives of it. It is shown that the effect of increasing the activity of bimetallic nanoparticles is due to the small size of particles (2–3 nm), compared to the monometallic palladium catalyst. It is established that the conversion of pyridine reaches 99% with 99% selectivity toward piperidine under mild conditions (60°C; H2 pressure, 70 atm).
- Keywords
- гидрирование пиридина пиперидин палладий медь серебро биметаллические наночастицы гетерогенные катализаторы
- Date of publication
- 12.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 11
References
- 1. Beletskaya I.P., Kustov L.M. // Russ. Chem. Rev. 2010. V. 79 (6). P. 441.
- 2. Zeolites and Zeolite-like Materials. Ed. by B.F. Sels, L.M. Kustov. 2016. P. 1–459.
- 3. Kustov L.M., Beletskaya I.P. // Ross. Khim. Zhurnal (Zhurnal Rossijskogo Khimicheskogo Obshchestva Im. D.I. Mendeleeva) 2004. V. 48 (6). P. 3.
- 4. Shesterkina A.A., Kustov L.M., Strekalova A.A. et al. // Catal. Sci. Technol. 2020. V. 10 (10). P. 3160.
- 5. Chernikova E.A., Glukhov L.M., Krasovskiy V.G. et al. // Russ. Chem. Rev. 2015. V. 84 (8). P. 875.
- 6. Kalenchuk A.N., Bogdan V.I., Dunaev S.F. et al. // Fuel Proc. Technol. 2018. V. 169. P. 94.
- 7. Sung J.S., Choo K.Y., Kim T.H. et al. // Int. J. Hydrogen Energy 2008. V. 33 (11). P. 2721.
- 8. Kalenchuk A., Bogdan V., Dunaev S. et al. // Fuel 2020. V. 280. P. 118625.
- 9. Tarasov A.L., Isaeva V.I., Tkachenko O.P. et al. // Fuel Proc. Technol. 2018. V. 176. P. 101.
- 10. Tursunov O., Kustov L., Tilyabaev Z. // J. Petroleum Sci. Eng. 2019. V. 180. P. 773.
- 11. Redina E.A., Vikanova K.V., Kapustin G.I. et al. // Eur. J. Org. Chem. 2019. V. 2019 (26). P. 4159.
- 12. Tkachenko O.P., Kustov L.M., Nikolaev S.A. et al. // Topics Catal. 2009. V. 52 (4). P. 344.
- 13. Redina E., Greish A., Novikov R. et al. // Appl. Catal. A: General 2015. V. 491. P. 170.
- 14. Bykov A., Matveeva V., Sulman M. et al. // Catal. Today. 2009. V. 140 (1–2). P. 64.
- 15. Redina E.A., Kirichenko O.A., Greish A.A. et al. // Catal. Today. 2015. V. 246. P. 216.
- 16. Isaeva V.I., Tkachenko O.P., Afonina E.V. et al. // Micropor. Mesopor. Mater. 2013. V. 166. P. 167.
- 17. ulman E.M., Matveeva V.G., Doluda V.Yu. et al. // Appl. Catal. B: Environmental 2010. V. 94 (1–2). P. 200
- 18. Tursunov O., Kustov L., and Kustov A. // Oil and Gas Sci. Technol. 2017. V. 72 (5). P. 30.
- 19. Tursunov O., Kustov L., and Tilyabaev Z. // J. Taiwan Inst. Chem. Engineers 2017. V. 78. P. 416.
- 20. Chen F., Li W., Sahoo B. et al. // Angew. Chemie Int. Ed. 2018. V. 57 (44). P. 14488.
- 21. Kokane R., Corre Y., Kemnitz E. et al. // New J. Chem. 2021. V. 45. P. 19572.
- 22. Yu X., Nie R., Zhang H. et al. // Micropor. Mesopor. Mater. 2018. V. 256. P. 10.
- 23. Hattori T., Ida T., Tsubone A. et al. // Eur. J. Org. Chem. 2015. V. 2015 (11). P. 2492.
- 24. Beckers N.A., Huynh S., Zhang X. et al. // ACS Catal. 2012. V. 2 (8). P. 1524.
- 25. Buil M.L., Esteruelas M.A., Niembro S. et al. // Organometallics 2010. V. 29 (19). P. 4375.
- 26. Maegawa T., Akashi A., Yaguchi K. et al. // Chem. A. Eur. J. 2009. V. 15 (28). P. 6953.
- 27. Irfan M., Petricci E., Glasnov T.N. et al. // Eur. J. Org. Chem. 2009. V. 9. P. 1327.
- 28. Barwinski B., Migowski P., Gallou F. et al. // J. Flow Chem. 2017. V. 7 (2). P. 41.
- 29. Kirichenko O.A., Redina E.A., Davshan N.A. et al. // Appl. Catal. B: Environmental 2013. V. 134–135. P. 123.
- 30. Kustov L.M. // Russ. J. Phys. Chem A 2015. V. 89 (11). P. 2006.
- 31. Mamonov N.A., Fadeeva E.V., Grigoriev D.A. et al. // Russ. Chem. Rev. 2013. V. 82 (6). P. 567.
- 32. Kustov A.L., Tkachenko O.P., Kustov L.M. et al. // Environment Int. 2011. V. 37 (6). P. 1053.
- 33. Mikhailov M.N., Kustov L.M., and Kazansky V.B. // Catal. Lett. 2008. V. 120 (1–2). P. 8.
- 34. Ivanov A.V., Koklin A.E., Uvarova E.B. et al. // Phys. Chem. Chem. Phys. 2003. V. 5 (20). P. 4718–4723.
- 35. Kumar N., Masloboischikova O.V., Kustov L.M. et al. // Ultrasonics Sonochem. 2007. V. 14 (2). P. 122.
- 36. Ivanov A.V., Kustov L.M. // Ross. Khim. Zhurnal (Zhurnal Rossijskogo Khimicheskogo Obshchestva Im. D.I. Mendeleeva). 2000. V. 44 (2). P. 21.
- 37. Vorob'eva M.P., Greish A.A., Ivanov A.V. et al. // Appl. Catal. A: General. 2000. V. 199 (2). P. 257.
- 38. Khodakov A.Yu., Kustov L.M., Kazansky V.B. et al. // J. Chem. Soc. Faraday Trans., 1993. V. 89 (9). P. 1393.
- 39. Kanazirev V., Dimitrova R., Price G.L. et al. // J. Molec. Catal. 1991. V. 70 (1). P. 111.
- 40. Kramareva N.V., Stakheev A.Yu., Tkachenko O.P. et al. // J. Molec. Catal. A: Chemical. 2004. V. 209 (1–2). P. 97.
