RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Phase Equilibria in H2O–CH3SO3H System: Experiment and Thermodynamic Modeling

PII
10.31857/S0044453723070038-1
DOI
10.31857/S0044453723070038
Publication type
Status
Published
Authors
Volume/ Edition
Volume 97 / Issue number 7
Pages
925-931
Abstract
Water activities in H2O–CH3SO3H system were obtained by the dew point method and by the static method of a vapor pressure measurement in a temperature range 288.15–323.15 K. Pitzer–Simonson–Clegg model parameters were calculated. The parameters describe adequately properties of a liquid phase in a temperature range 198.15–323.15 К and with an acid concentration up to 80 wt %. Stability parameters were determined for two solid phases, HMS·H2O and HMS·3H2O (HMS = CH3SO3H).
Keywords
метансульфоновая кислота модель Питцера–Симонсона–Клегга статический метод давления пара метод точки росы фазовая диаграмма
Date of publication
12.09.2025
Year of publication
2025
Number of purchasers
0
Views
8

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