- PII
- 10.31857/S0044453723110043-1
- DOI
- 10.31857/S0044453723110043
- Publication type
- Status
- Published
- Authors
- Volume/ Edition
- Volume 97 / Issue number 11
- Pages
- 1611-1619
- Abstract
- The electronic properties of weak and strong tetrel bonds (TtBs) formed by the elements of the carbon subgroup Tt = C, Si, Ge, Sn, Pb, which provide their subatomic electrophilic site for noncovalent interactions, have been studied. Generalized quantitative models for evaluating the energy of tetrel bonds were obtained for a large sample of molecular complexes formed by halide anions or ammonia molecule with tetrahedral molecules used as an example. The replacement of the nucleophilic fragment in the complexes leads to different trends for the dependences of the interaction energy on the electronic characteristic of the bond. The minimum of the electrostatic potential on the line of the tetrel bond proved to be the most universal factor suitable for quantitative comparison of both weak and relatively strong bonds within a single parametric model.
- Keywords
- тетрельная связь электронная плотность электростатический потенциал потенциал действующий на электрон в молекуле
- Date of publication
- 12.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 2
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