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RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Some electrochemical phenomena accompanying destruction of nanocluster polyoxomolybdate Mo132

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PII
S0044453725020157-1
DOI
10.31857/S0044453725020157
Publication type
Article
Status
Published
Authors
A. A. Остроушко
  • Affiliation: Ural Federal University named after the first President of Russia B. N. Yeltsin
Volume/ Edition
Volume 99 / Issue number 2
Pages
297-303
Abstract
During thermodestruction of keplerate-type nanocluster polyoxometallate (POM) Mo132 in the solid state, there were electric charges in the samples due to the release of amphiphilic ionized molecular particles into the environment. The sample-ground potential difference reached 100 and more volts, and the sign of the charge was determined by the presence or absence of the moderate electromagnetic field. In the course of studying the photodegradation of POM Mo132 in aqueous solutions, an electrochemical phenomenon such as the occurrence of photovoltaic potential difference between the electrodes placed in the solution from the top and bottom is observed. The fluctuations of the potential difference due to the processes of polarization/depolarization of the near-electrode zones caused by different diffusion rates of counterions from the upper and lower parts of the solution are also found.
Keywords
нанокластерный полиоксометаллат электрохимические явления термодеструкция растворы окислительная фотодеструкция колебательные процессы
Date of publication
12.09.2025
Year of publication
2025
Number of purchasers
0
Views
11

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