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RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

SORPTION CAPACITY OF POLYMER BASED ON CARBOXYMETHYLCELLULOSE AND GLYCIDYLACRYLATE TOWARDS METAL IONS

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PII
S3034553725070151-1
DOI
10.7868/S3034553725070151
Publication type
Article
Status
Published
Authors
V.A. Lipin
  • Affiliation: Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design
A.N. Evdokimov
  • Affiliation: Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design
Y.A. Petrova
  • Affiliation: Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design
D.D. Hernandez Garcia
  • Affiliation: Graduate School of Technology and Energy, St. Petersburg State University of Industrial Technologies and Design
I.V. Krasanov
  • Affiliation: St. Petersburg State Maritime Technical University
A.V. Dmitrieva
  • Affiliation: St. Petersburg State Maritime Technical University
V.E. Sitnikova
  • Affiliation: ITMO National Research University
Volume/ Edition
Volume 99 / Issue number 7
Pages
1094-1101
Abstract
The sorption ability of the synthesized polymer based on carboxymethylcellulose and glycidylacrylate towards Cu, Ni, Fe, Mn ions has been studied. It has been shown that the sorption of metal ions is reliably described by the Langmuir model, and the process itself has a physical character. By the method of thermogravimetric analysis it has been established that the process of thermodegradation of the polymer occurs in three steps, and of its complex with copper – in four steps. The activation energy of decomposition of the initial polymer for each step is in the range of 29–57 kJ/mol, and for its complex with copper – 58–120 kJ/mol. The introduction of Cu(II) increases the thermostability of the obtained polymer based on carboxymethylcellulose.
Keywords
глицидилакрилат карбоксиметилцеллюлоза сорбция ионы тяжелых металлов
Date of publication
30.01.2025
Year of publication
2025
Number of purchasers
0
Views
28

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