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RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

THERMODYNAMIC CHARACTERISTICS OF COMPLEX FORMATION OF L-LYSINE WITH ISOMERS OF PYRIDINEMONOCARBOXYLIC ACID IN AQUEOUS SOLUTION

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PII
S3034553725100062-1
DOI
10.7868/S3034553725100062
Publication type
Article
Status
Published
Authors
E.Yu. Tyunina
  • Affiliation: Krestov Institute of Solution Chemistry, Russian Academy of Sciences
I.N. Mezhevoi
  • Affiliation: Krestov Institute of Solution Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 99 / Issue number 10
Pages
1497-1504
Abstract
The interactions of the polar basic amino acid L-lysine (Lys) with structural isomers of pyridine monocarboxylic acid: picolinic (PA), nicotinic (NA) and isonicotinic (INA) acids in an aqueous solution were studied by solution calorimetry at 298.15 K. The experimental data allowed us to establish the formation of Lys complexes with the indicated isomers with a stoichiometry of 1:1. The thermodynamic parameters were determined: binding constants, enthalpies of complex formation, Gibbs energies and entropies. The stability of the formed complexes depends on the structural isomerism of pyridine carboxylic acid and increases in the series: PA < NA < INA. It was shown that the main contribution to the stabilization of the formed complexes is made by the enthalpic component of the Gibbs free energy of complex formation.
Keywords
энтальпия растворения L-лизин пиколиновая кислота никотиновая кислота изоникотиновая кислота водный раствор комплексообразование
Date of publication
18.04.2025
Year of publication
2025
Number of purchasers
0
Views
31

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