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RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

SORPTION OF METHYLENE BLUE BY POLISORB MP FROM WATER AND 40% AND 95% AQUEOUS-ETHANOL SOLUTIONS

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PII
S3034553725100116-1
DOI
10.7868/S3034553725100116
Publication type
Article
Status
Published
Authors
T.Yu. Podlipskaya
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
M.K. Barakina
  • Affiliation:
    Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
    Novosibirsk State University
M.G. Demidova
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
N.O. Shaparenko
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
V.V. Tatarchuk
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
P.E. Plyusnin
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
E.A. Maksimovskiy
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
T.Ya. Guselnikova
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
E.V. Polyakova
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
A.I. Bulavchenko
  • Affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Volume/ Edition
Volume 99 / Issue number 10
Pages
1540-1555
Abstract
The chemical composition of the medical enterosorbent Polisorb MP (colloidal silica particles) and its surrounding dispersive medium was determined using AES ICP, CHNS analysis, TGA, and capillary electrophoresis. Dispersions of Polisorb in water and in 40% and 95% aqueous-ethanol solutions were prepared and characterized by photon correlation spectroscopy (PCS) and phase analysis light scattering (PALS). The number-average hydrodynamic diameter of fractal-like aggregates of primary particles was 105 – 135 nm, and the electrophoretic potential ranged from –28 to –22 mV. The charge of a single aggregate decreased with increasing alcohol content in the sequence: –89, –54, and –29 e. The maximum sorption of methylene blue sharply decreased from 10 to 0.7 mg/g under these conditions. It was shown that the maximum sorption values significantly exceed the number of negative surface centers calculated by PALS within the spherical aggregate model, but are lower than the number of silanol groups determined by TGA. A cation-exchange mechanism for the sorption of cationic dyes by Polisorb MP is hypothesized.
Keywords
адсорбция микроэмульсии бис(2-этилгексил) сульфосукцинат натрия наночастицы SiO метиленовый синий
Date of publication
26.03.2025
Year of publication
2025
Number of purchasers
0
Views
30

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