RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

RHEOLOGY OF THIXOTROPIC DISPERSIONS. TRANSIENT PHENOMENA WITH INCREASING SHEAR RATE

PII
S30345537S0044453725040086-1
DOI
10.7868/S3034553725040086
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 99 / Issue number 4
Pages
595-604
Abstract
A structural rheological model is used to describe the thixotropic dispersed system of silicon dioxide in oil. The model includes a kinetic equation of the processes of formation and destruction of particle aggregates and a rheological equation containing a structural parameter (the number of aggregated particles in a unit volume). The case of an equilibrium plastic flow, which corresponds to experimental flow curves, is considered. The coefficients of the rheological equation are calculated. For a stepwise increase in the shear rate from γ1 to γ2 , the transient process is considered as a transition from one equilibrium state of the flow to another equilibrium state through a certain nonequilibrium state of the flow. The coefficient of deviation from equilibrium is introduced, and its dependence ζ(t) is calculated using exponential functions; the limiting value ζ0 is determined. The transient dependences τ1/2(t) are approximated.
Keywords
дисперсная система тиксотропные свойства структурная реологическая модель кривые течения переходный процесс при увеличении скорости сдвига
Date of publication
15.04.2025
Year of publication
2025
Number of purchasers
0
Views
28

References

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  5. 5. Кирсанов Е.А., Матвеенко В.Н. Неньютоновское течение дисперсных, полимерных и жидкокристаллических систем. Структурный подход: монография М.: Техносфера, 2016. 384 с.@@ Kirsanov E.A., Matveenko V.N. Non-Newtonian flow of dispersed, polymer and liquid crystal systems. Structural approach. Moscow: Technosphere, 2016, 384 p. (in Russ.).
  6. 6. Кирсанов Е.А., Матвеенко В.Н. Вязкость и упругость структурированных жидкостей: монография М.: Техносфера, 2022. 284 с.@@ Kirsanov E.A., Matveenko V.N. Viscosity and elasticity of structured liquids. Moscow: Technosphere, 2022, 284 p. (in Russ.).
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