RAS Chemistry & Material ScienceЖурнал физической химии Russian Journal of Physical Chemistry

  • ISSN (Print) 0044-4537
  • ISSN (Online) 3034-5537

Potassium–Sodium Ceramics Modified with Metal Oxide Additives: Synthesis, Microstructure, and Properties

PII
10.31857/S0044453723010144-1
DOI
10.31857/S0044453723010144
Publication type
Status
Published
Authors
Volume/ Edition
Volume 97 / Issue number 1
Pages
95-100
Abstract
Single phase ceramic samples of new compounds (1 − x)(K0.5Na0.5)NbO3−xLa(Ag0.5Sb0.5)O3 (x = 0–0.15), modified by metal oxide additives ZnO, CuO, and MnO2, are prepared via a solid state reaction. The crystal structure, microstructure, and dielectric and ferroelectric properties of the samples are studied. It is established that a phase with a perovskite structure and an orthorhombic unit cell formed in each sample. Ferroelectric phase transitions are confirmed via dielectric spectroscopy. Generation of the second harmonic is observed, along with a drop in the temperature of transitions from the ferroelectric orthorhombic phase to the ferroelectric tetragonal phase, and then to the cubic paraelectric phase.
Keywords
ниобат калия-натрия керамика структура перовскита диэлектрические свойства
Date of publication
13.09.2025
Year of publication
2025
Number of purchasers
0
Views
14

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